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学科主题: 金属有机化学
题名: Oxidative C(Sp(3))-H activation and C-N cleavage of N-methyl amines under transition-metal-free condition for synthesis of methylene-bridged bis-1,3-diketones
其他题名: 无过渡金属催化的N-甲基胺的C(sp3)-H键氧化活化以及C-N键裂解制备亚甲基桥联的1,3-二酮化合物
作者: Wang XH(王小虎)1; Wang Y(王漪)1; Yuan Y(袁宇)1; Xing CH(邢春晖)1
通讯作者: 袁宇 ; 邢春晖
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.01.033
卷: 70, 期:12, 页:2195-2202
收录类别: SCI
英文摘要: A transition-metal-free oxidative methylenation reaction was developed. Methylene-bridged bis-1,3-dicarbonyl compounds were synthesized by oxidative C(Sp(3))-H activation and C-N cleavage of N-methyl amines. This novel reaction avoids the use of transition metal catalyst. Furthermore, the reaction are very mild and operational convenient. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39041
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.扬州大学
2.中科院上海有机化学研究所

Recommended Citation:
Wang XH,Wang Y,Yuan Y,et al. Oxidative C(Sp(3))-H activation and C-N cleavage of N-methyl amines under transition-metal-free condition for synthesis of methylene-bridged bis-1,3-diketones[J]. Tetrahedron,2014,70(12):2195-2202.
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