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学科主题: 金属有机化学
题名: A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums
其他题名: 一种通过CuBr催化高炔丙胺的串联反应构建C=C-CF3片段的新策略: 高效合成含三氟甲基的切块4-三氟甲基-3,4-二氢吡咯盐
作者: Ge GC(葛广存); Huang XJ(黄小军); Ding CH(丁昌华); Wan SL(万世力); Dai LX(戴立信); Hou XL(侯雪龙)
通讯作者: 丁昌华 ; 侯雪龙
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c3cc49059a
卷: 50, 期:23, 页:3048-3051
收录类别: SCI
英文摘要: A new strategy for the construction of a C=C-CF3 subunit has been developed via CuBr-catalyzed domino cyclization-trifluoromethylation of homopropargyl amines with Umemoto's reagent. 4-Trifluoromethyl-2,3- dihydro-pyrroliums were produced in high yields. The usefulness of these products has been demonstrated by the transformation of them into various other trifluoromethylated molecules.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39038
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Ge GC,Huang XJ,Ding CH,et al. A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums[J]. Chem. Commun.,2014,50(23):3048-3051.
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