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A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums
Alternative Title一种通过CuBr催化高炔丙胺的串联反应构建C=C-CF3片段的新策略: 高效合成含三氟甲基的切块4-三氟甲基-3,4-二氢吡咯盐
Ge GC(葛广存); Huang XJ(黄小军); Ding CH(丁昌华); Wan SL(万世力); Dai LX(戴立信); Hou XL(侯雪龙)
2014
Source PublicationChem. Commun.
Volume50Issue:23Pages:3048-3051
AbstractA new strategy for the construction of a C=C-CF3 subunit has been developed via CuBr-catalyzed domino cyclization-trifluoromethylation of homopropargyl amines with Umemoto's reagent. 4-Trifluoromethyl-2,3- dihydro-pyrroliums were produced in high yields. The usefulness of these products has been demonstrated by the transformation of them into various other trifluoromethylated molecules.
Subject Area金属有机化学
DOI10.1039/c3cc49059a
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Indexed BySCI
Language英语
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Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39038
Collection金属有机化学国家重点实验室
Corresponding AuthorDing CH(丁昌华); Hou XL(侯雪龙)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Ge GC,Huang XJ,Ding CH,et al. A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums[J]. Chem. Commun.,2014,50(23):3048-3051.
APA 葛广存,黄小军,丁昌华,万世力,戴立信,&侯雪龙.(2014).A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.Chem. Commun.,50(23),3048-3051.
MLA 葛广存,et al."A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums".Chem. Commun. 50.23(2014):3048-3051.
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