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学科主题: 金属有机化学
题名: Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles
其他题名: 铱催化的吲哚的分子间不对称烯丙基去芳构化
作者: Zhang X(张霄); Han L(韩龙); You SL(游书力)
通讯作者: 游书力
刊名: Chem. Sci.
发表日期: 2014
DOI: 10.1039/c3sc53019a
卷: 5, 期:3, 页:1059-1063
收录类别: SCI
英文摘要: An Ir-catalyzed intermolecular asymmetric dearomatization reaction of substituted indoles with allylic alcohols has been realized to afford the corresponding indoline derivatives in 71-97% yield with up to 98% ee in the presence of the Lewis acid Fe(OTf)(2). This methodology features the enantioselective construction of all-carbon quaternary stereogenic centers of prochiral nucleophiles and its utility has been demonstrated in the asymmetric total synthesis of (-)-debromoflustramine B.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39036
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhang X,Han L,You SL. Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles[J]. Chem. Sci.,2014,5(3):1059-1063.
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