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Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles
Alternative Title铱催化的吲哚的分子间不对称烯丙基去芳构化
Zhang X(张霄); Han L(韩龙); You SL(游书力)
2014
Source PublicationChem. Sci.
Volume5Issue:3Pages:1059-1063
AbstractAn Ir-catalyzed intermolecular asymmetric dearomatization reaction of substituted indoles with allylic alcohols has been realized to afford the corresponding indoline derivatives in 71-97% yield with up to 98% ee in the presence of the Lewis acid Fe(OTf)(2). This methodology features the enantioselective construction of all-carbon quaternary stereogenic centers of prochiral nucleophiles and its utility has been demonstrated in the asymmetric total synthesis of (-)-debromoflustramine B.
Subject Area金属有机化学
DOI10.1039/c3sc53019a
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Indexed BySCI
Language英语
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Cited Times:79[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39036
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhang X,Han L,You SL. Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles[J]. Chem. Sci.,2014,5(3):1059-1063.
APA 张霄,韩龙,&游书力.(2014).Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles.Chem. Sci.,5(3),1059-1063.
MLA 张霄,et al."Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles".Chem. Sci. 5.3(2014):1059-1063.
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