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Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate
Alternative Title三氟甲磺酸钪催化的2,3-二取代吲哚的C6直接官能团化
Liu H(刘华); Zheng C(郑超); You SL(游书力)
2014
Source PublicationJ. Org. Chem.
Volume79Issue:3Pages:1047-1054
AbstractWe report herein an unprecedented direct catalytic C6 functionalization reaction of 2,3-disubstituted indoles with various N-Ts aziridines catalyzed by Sc(OTf)(3) under mild conditions. Mechanistic studies revealed that a kinetically favored but reversible formal [3 + 2] annulation occurs initially. The direct C6 functionalization, although having a relatively higher energetic barrier, delivers the thermodynamically favorable products.
Subject Area金属有机化学
DOI10.1021/jo402511b
URL查看原文
Indexed BySCI
Language英语
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Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39034
Collection金属有机化学国家重点实验室
Corresponding AuthorZheng C(郑超); You SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Liu H,Zheng C,You SL. Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate[J]. J. Org. Chem.,2014,79(3):1047-1054.
APA 刘华,郑超,&游书力.(2014).Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate.J. Org. Chem.,79(3),1047-1054.
MLA 刘华,et al."Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate".J. Org. Chem. 79.3(2014):1047-1054.
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