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学科主题: 金属有机化学
题名: Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate
其他题名: 三氟甲磺酸钪催化的2,3-二取代吲哚的C6直接官能团化
作者: Liu H(刘华); Zheng C(郑超); You SL(游书力)
通讯作者: 郑超 ; 游书力
刊名: J. Org. Chem.
发表日期: 2014
DOI: 10.1021/jo402511b
卷: 79, 期:3, 页:1047-1054
收录类别: SCI
英文摘要: We report herein an unprecedented direct catalytic C6 functionalization reaction of 2,3-disubstituted indoles with various N-Ts aziridines catalyzed by Sc(OTf)(3) under mild conditions. Mechanistic studies revealed that a kinetically favored but reversible formal [3 + 2] annulation occurs initially. The direct C6 functionalization, although having a relatively higher energetic barrier, delivers the thermodynamically favorable products.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39034
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Liu H,Zheng C,You SL. Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate[J]. J. Org. Chem.,2014,79(3):1047-1054.
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