| Stereospecific synthesis of highly functionalized benzo[3.1.0]bicycloalkanes via multistep cascade reactions | |
| Alternative Title | 多步串联反应立体专一性合成高官能团化的苯并[3.1.0]双环烷烃结构 |
| Zhu JB(朱剑波); Chen H(陈昊); Wang LJ(王丽佳); Tang Y(唐勇) | |
| 2014 | |
| Source Publication | Org. Chem. Front.
 |
| Volume | 1Pages:965-968 |
| Abstract | A facile approach for the synthesis of benzo[3.1.0]bicycloalkanes via alkylation/cyclopropanation cascade reactions of benzyl bromide with triphenylphosphonium bromide has been developed. By elaborate designing of starting materials, this multistep cyclization proceeded smoothly with a wide range of substrates, providing the benzo[3.1.0]bicycloalkanes in 52–90% yields with exclusive diastereoselectivity. |
| Subject Area | 金属有机化学 |
| DOI | 10.1039/c4qo00134f |
| URL | 查看原文 |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39031 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Tang Y(唐勇) |
| Affiliation | 中科院上海有机化学研究所 |
| Recommended Citation GB/T 7714 | Zhu JB,Chen H,Wang LJ,et al. Stereospecific synthesis of highly functionalized benzo[3.1.0]bicycloalkanes via multistep cascade reactions[J]. Org. Chem. Front.,2014,1:965-968. |
| APA | 朱剑波,陈昊,王丽佳,&唐勇.(2014).Stereospecific synthesis of highly functionalized benzo[3.1.0]bicycloalkanes via multistep cascade reactions.Org. Chem. Front.,1,965-968. |
| MLA | 朱剑波,et al."Stereospecific synthesis of highly functionalized benzo[3.1.0]bicycloalkanes via multistep cascade reactions".Org. Chem. Front. 1(2014):965-968. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2014069.pdf（328KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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