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Ozonation of Methylenecyclopropanes
Alternative Title亚甲基环丙烷的臭氧化反应
Sang R(桑睿); Tang XY(唐翔鹰); Shi M(施敏)
Source PublicationOrg. Chem. Front.
AbstractOzonation of methylenecyclopropanes bearing gem-disubstituted electron-withdrawing groups (EWG) gave ring-opened oxidative products in moderate to good yields. For MCPs in which EWGs are two methoxycarbonyl groups, the ozonation gave oxidative cyclization products in methanol at ?78 °C in the presence of CuCl; for MCPs in which EWGs are one methoxycarbonyl and one trifluoromethyl group, the ozonation produced α-diketones in ethyl acetate (EA) at ?78 °C.
Subject Area金属有机化学
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Document Type期刊论文
Corresponding AuthorShi M(施敏)
Recommended Citation
GB/T 7714
Sang R,Tang XY,Shi M. Ozonation of Methylenecyclopropanes[J]. Org. Chem. Front.,2014,1:770-773.
APA 桑睿,唐翔鹰,&施敏.(2014).Ozonation of Methylenecyclopropanes.Org. Chem. Front.,1,770-773.
MLA 桑睿,et al."Ozonation of Methylenecyclopropanes".Org. Chem. Front. 1(2014):770-773.
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