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学科主题: 金属有机化学
题名: Ozonation of Methylenecyclopropanes
其他题名: 亚甲基环丙烷的臭氧化反应
作者: Sang R(桑睿); Tang XY(唐翔鹰); Shi M(施敏)
通讯作者: 施敏
刊名: Org. Chem. Front.
发表日期: 2014
DOI: 10.1039/c4qo00160e
卷: 1, 页:770-773
英文摘要: Ozonation of methylenecyclopropanes bearing gem-disubstituted electron-withdrawing groups (EWG) gave ring-opened oxidative products in moderate to good yields. For MCPs in which EWGs are two methoxycarbonyl groups, the ozonation gave oxidative cyclization products in methanol at ?78 °C in the presence of CuCl; for MCPs in which EWGs are one methoxycarbonyl and one trifluoromethyl group, the ozonation produced α-diketones in ethyl acetate (EA) at ?78 °C.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39027
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Sang R,Tang XY,Shi M. Ozonation of Methylenecyclopropanes[J]. Org. Chem. Front.,2014,1:770-773.
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