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学科主题: 金属有机化学
题名: Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives
其他题名: 银催化的亚甲基环丙烷C-O键和C-C键的断裂反应-功能团化三氟甲基醋酸酯延生物的构建
作者: Chen GQ(陈根强); Tang XY(唐翔鹰); Shi M(施敏)
通讯作者: 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2014
DOI: 10.1002/ejoc.201301262
卷: 2014, 期:1, 页:194-197
收录类别: SCI
英文摘要: The reaction of methylenecyclopropanes (MCPs) with tetrahydrofuran (THF) proceed smoothly in the presence of AgOC(O)CF3 and electrophilic halogenation reagents to give the corresponding 4-(3-halobut-3-enyloxy)butyl 2,2,2-trifluoroacetate derivatives in moderate yields through dual cleavage of C-C and C-O bonds under mild conditions.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39025
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Chen GQ,Tang XY,Shi M. Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives[J]. Eur. J. Org. Chem.,2014,2014(1):194-197.
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