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Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives
Alternative Title银催化的亚甲基环丙烷C-O键和C-C键的断裂反应-功能团化三氟甲基醋酸酯延生物的构建
Chen GQ(陈根强); Tang XY(唐翔鹰); Shi M(施敏)
2014
Source PublicationEur. J. Org. Chem.
Volume2014Issue:1Pages:194-197
AbstractThe reaction of methylenecyclopropanes (MCPs) with tetrahydrofuran (THF) proceed smoothly in the presence of AgOC(O)CF3 and electrophilic halogenation reagents to give the corresponding 4-(3-halobut-3-enyloxy)butyl 2,2,2-trifluoroacetate derivatives in moderate yields through dual cleavage of C-C and C-O bonds under mild conditions.
Subject Area金属有机化学
DOI10.1002/ejoc.201301262
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39025
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Chen GQ,Tang XY,Shi M. Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives[J]. Eur. J. Org. Chem.,2014,2014(1):194-197.
APA 陈根强,唐翔鹰,&施敏.(2014).Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives.Eur. J. Org. Chem.,2014(1),194-197.
MLA 陈根强,et al."Silver(I)-Mediated Dual Cleavage of C-C and C-O Bonds in the Reaction of Diarylmethylenecyclopropanes with Tetrahydrofuran: Synthesis of 4-(3-Halobut-3-enyloxy)butyl 2,2,2-Trifluoroacetate Derivatives".Eur. J. Org. Chem. 2014.1(2014):194-197.
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