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Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups
Alternative Title钯催化二芳基膦氢对α,β,γ,δ-磺酸酯不饱和共轭二烯的不对称1,6加成反应
Lu JZ(陆俊筑)1; Ye JX(叶金星)1; Duan WL(段伟良)1
2014
Source PublicationChem. Commun.
Volume50Issue:6Pages:698-700
AbstractPalladium-catalyzed asymmetric 1,6-addition of diarylphosphines to electron-deficient dienes was developed through rational selection of electron-withdrawing groups on the dienes. Various chiral allylic phosphine derivatives were synthesized in good yields with high enantioselectivity (up to 96% ee).
Subject Area金属有机化学
DOI10.1039/c3cc46290k
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Indexed BySCI
Language英语
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Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39024
Collection金属有机化学国家重点实验室
Corresponding AuthorDuan WL(段伟良)
Affiliation1.中科院上海有机化学研究所
2.华东理工大学
Recommended Citation
GB/T 7714
Lu JZ,Ye JX,Duan WL. Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups[J]. Chem. Commun.,2014,50(6):698-700.
APA 陆俊筑,叶金星,&段伟良.(2014).Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups.Chem. Commun.,50(6),698-700.
MLA 陆俊筑,et al."Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups".Chem. Commun. 50.6(2014):698-700.
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