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学科主题: 金属有机化学
题名: Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups
其他题名: 钯催化二芳基膦氢对α,β,γ,δ-磺酸酯不饱和共轭二烯的不对称1,6加成反应
作者: Lu JZ(陆俊筑)1; Ye JX(叶金星)1; Duan WL(段伟良)1
通讯作者: 段伟良
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c3cc46290k
卷: 50, 期:6, 页:698-700
收录类别: SCI
英文摘要: Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to electron-deficient dienes was developed through rational selection of electron-withdrawing groups on the dienes. Various chiral allylic phosphine derivatives were synthesized in good yields with high enantioselectivity (up to 96% ee).
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39024
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.华东理工大学

Recommended Citation:
Lu JZ,Ye JX,Duan WL. Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to alpha,beta,gamma,delta-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups[J]. Chem. Commun.,2014,50(6):698-700.
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