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学科主题: 金属有机化学
题名: Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity
其他题名: 钯催化硝基甲烷和二烯基碳酸酯的高C-5位区域选择性的烯丙基烷基化反应
作者: Yang XF(杨晓菲); Li XH(李小惠); Ding CH(丁昌华); Dai LX(戴立信); Hou XL(侯雪龙)
通讯作者: 丁昌华 ; 侯雪龙
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c3cc46574h
卷: 50, 期:4, 页:484-486
收录类别: SCI
英文摘要: A highly regioselective palladium-catalyzed allylic alkylation of dienyl esters with nitromethane has been developed, providing selective access to the C-5 attacked products. The structures of the ligands as well as the steric effect of the substrates are important factors in determining the regiochemical outcome of the reaction.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39023
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Yang XF,Li XH,Ding CH,et al. Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity[J]. Chem. Commun.,2014,50(4):484-486.
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