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学科主题: 金属有机化学
题名: Enantioselective Double Manipulation of Tetrahydroisoquinolines with Terminal Alkynes and Aldehydes under Copper(I) Catalysis
其他题名: 铜(I)催化的对映选择性的四氢异喹啉、末端炔和醛的反应
作者: Lin WL(林渭龙)1; Cao T(曹陶)1; Fan W(范武)1; Han YL(韩玉林)1; Kuang JQ(况锦强)1; Luo HW(罗鸿文)1; 缪不可言1; Tang XJ(汤鑫军)1; Yu Q(俞琼)1; Yuan WM(袁伟民)1; Zhang JS(张加生)1; Zhu C(朱灿)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201308699
卷: 53, 期:1, 页:277-281
收录类别: SCI
英文摘要: Tetrahydroisoquinoline alkaloids with a C1 stereogenic center are a common unit in many natural and non-natural compounds of biological importance. Herein we describe a novel Cu-I-catalyzed highly chemo- and enantioselective synthesis of chiral tetrahydroisoquinoline-alkaloid derivatives from readily available unsubstituted tetrahydroisoquinolines, aldehydes, and terminal alkynes in the presence of the ligand (R,R)-N-pinap. This synthetic operation installs two substituents in the 1- and 2-positions.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39010
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.华东师范大学

Recommended Citation:
Lin WL,Cao T,Fan W,et al. Enantioselective Double Manipulation of Tetrahydroisoquinolines with Terminal Alkynes and Aldehydes under Copper(I) Catalysis[J]. Angew. Chem.-Int. Edit.,2014,53(1):277-281.
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