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Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins
Alternative Title钯催化烯丙基取代反应对4-取代-3,4-二氢苯并吡喃酮的动力学拆分: 反式-3,4-二取代-3,4-二氢苯并吡喃酮的对映选择性合成
Li XH(李小惠); Fang P(方萍); Chen D(陈娣); Hou XL(侯雪龙)
2014
Source PublicationOrg. Chem. Front.
Volume1Pages:969-973
AbstractThe kinetic resolution of 4-substituted-3,4-dihydrocoumarins was realized via Pd-catalyzed allylic substitution reaction using Trost’s chiral ligand L12, affording optically active mono- and trans-3,4-disubstituted dihydrocoumarin derivatives in high yields and with high enantioselectivities with an S factor up to 55.
Subject Area金属有机化学
DOI10.1039/c4qo00178h
URL查看原文
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39009
Collection金属有机化学国家重点实验室
Corresponding AuthorHou XL(侯雪龙)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Li XH,Fang P,Chen D,et al. Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins[J]. Org. Chem. Front.,2014,1:969-973.
APA 李小惠,方萍,陈娣,&侯雪龙.(2014).Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins.Org. Chem. Front.,1,969-973.
MLA 李小惠,et al."Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins".Org. Chem. Front. 1(2014):969-973.
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