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学科主题: 金属有机化学
题名: Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds
其他题名: 钯催化二取代膦氢对不饱和羰基化合物的1.4加成缺电子烯烃: 合成含膦手性和碳手性的膦化合物
作者: Li C(李春); Li WX(李伟逊); Xu S(许胜); Duan WL(段伟良)
通讯作者: 段伟良
刊名: Org. Chem. Front.
发表日期: 2014
DOI: 10.1039/c4qo00017j
卷: 1, 页:541-545
英文摘要: Highly stereoselective 1,4-addition of alkylphenylphosphines to α,β-unsaturated carbonyl compounds catalyzed by PCP or NCN pincer–Pd complexes is described to synthesize chiral phosphorus compounds earing both P- and C-stereogenic centers with good to excellent enantioselectivity (up to 99.6% ee).
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39004
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Li C,Li WX,Xu S,et al. Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds[J]. Org. Chem. Front.,2014,1:541-545.
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