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Formal synthesis of osladin based on an activation relay process
Alternative TitleFormal synthesis of osladin based on an activation relay process
Zhang XF(张晓菲)1; Wu JJ(吴晶晶)1; Shi Y(史勇)1; Lin JR(林静容)1; Tian WS(田伟生)1
2014
Source PublicationTetrahedron Lett.
Volume55Issue:33Pages:4639-4642
AbstractAn efficient five-step formal synthesis of osladin by utilizing the intact skeleton of diosgenin acetate is reported. Key features of this study include an unprecedented reductive opening of E-ring in steroidal sapogenin to give 22S-5, and an activation relay process for selective breakage of C16-O bond in furostanol to deliver 22R-17. (C) 2014 Elsevier Ltd. All rights reserved.
Subject Area天然产物有机化学
DOI10.1016/j.tetlet.2014.06.101
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38986
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorShi Y(史勇); Lin JR(林静容); Tian WS(田伟生)
Affiliation1.上海师范大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhang XF,Wu JJ,Shi Y,et al. Formal synthesis of osladin based on an activation relay process[J]. Tetrahedron Lett.,2014,55(33):4639-4642.
APA 张晓菲,吴晶晶,史勇,林静容,&田伟生.(2014).Formal synthesis of osladin based on an activation relay process.Tetrahedron Lett.,55(33),4639-4642.
MLA 张晓菲,et al."Formal synthesis of osladin based on an activation relay process".Tetrahedron Lett. 55.33(2014):4639-4642.
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