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学科主题: 天然产物有机化学
题名: Formal synthesis of osladin based on an activation relay process
其他题名: Formal synthesis of osladin based on an activation relay process
作者: Zhang XF(张晓菲)1; Wu JJ(吴晶晶)1; Shi Y(史勇)1; Lin JR(林静容)1; Tian WS(田伟生)1
通讯作者: 史勇 ; 林静容 ; 田伟生
刊名: Tetrahedron Lett.
发表日期: 2014
DOI: 10.1016/j.tetlet.2014.06.101
卷: 55, 期:33, 页:4639-4642
收录类别: SCI
英文摘要: An efficient five-step formal synthesis of osladin by utilizing the intact skeleton of diosgenin acetate is reported. Key features of this study include an unprecedented reductive opening of E-ring in steroidal sapogenin to give 22S-5, and an activation relay process for selective breakage of C16-O bond in furostanol to deliver 22R-17. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38986
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.上海师范大学
2.中科院上海有机化学研究所

Recommended Citation:
Zhang XF,Wu JJ,Shi Y,et al. Formal synthesis of osladin based on an activation relay process[J]. Tetrahedron Lett.,2014,55(33):4639-4642.
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