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学科主题: 天然产物有机化学
题名: Highly Efficient and Scalable Synthesis of Clionamine D
其他题名: Highly Efficient and Scalable Synthesis of Clionamine D
作者: Wang SS(王莎莎); Shi Y(史勇); Tian WS(田伟生)
通讯作者: 史勇 ; 田伟生
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol500727c
卷: 16, 期:8, 页:2177-2179
收录类别: SCI
英文摘要: Herein we describe an efficient and scalable synthesis of clionamine D (4), a special member with autophagy bioactivity and an unprecedented spirobislactone side chain in the novel aminosteroid clionamines. This synthesis features a quick access to alpha-methylene-gamma-lactone 8 and a Mn(OAc)(3)-mediated radical [3 + 2] reaction to assemble the unique spirobislactone unit. Clionamine D (4) can also serve as a key synthetic precursor to other clionamine members.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38980
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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Wang SS,Shi Y,Tian WS. Highly Efficient and Scalable Synthesis of Clionamine D[J]. Org. Lett.,2014,16(8):2177-2179.
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