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学科主题: 天然产物有机化学
题名: Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center
其他题名: 氮-乙酰基氨基膦催化氧化吲哚对联烯酸酯不对称加成: 构筑含季碳中心的官能化的氧化吲哚
作者: Chen JH(陈锦浩)1; Cai YP(蔡跃鹏)1; Zhao G(赵刚)1
通讯作者: 蔡跃鹏 ; 赵刚
刊名: Adv. Synth. Catal.
发表日期: 2014
DOI: 10.1002/adsc.201300695
卷: 356, 期:2-3, 页:359-363
收录类别: SCI
英文摘要: A novel reaction between ethyl allenoate and oxindoles that enables the asymmetric synthesis of 3,3-bisubstituted oxindoles with our previously established bifunctional N-acyl aminophosphine catalysts is reported. These products bearing a chiral quaternary carbon center at the C-3 position of the oxindoles may have potential significance in the synthesis of related structures. The best performance of these processes provides adducts with 92% yield and 94% ee. imageWILEY-VCH
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38972
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.华南师范大学
2.中科院上海有机化学研究所

Recommended Citation:
Chen JH,Cai YP,Zhao G. Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center[J]. Adv. Synth. Catal.,2014,356(2-3):359-363.
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