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Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center
Alternative Title氮-乙酰基氨基膦催化氧化吲哚对联烯酸酯不对称加成: 构筑含季碳中心的官能化的氧化吲哚
Chen JH(陈锦浩)1; Cai YP(蔡跃鹏)1; Zhao G(赵刚)1
2014
Source PublicationAdv. Synth. Catal.
Volume356Issue:2-3Pages:359-363
AbstractA novel reaction between ethyl allenoate and oxindoles that enables the asymmetric synthesis of 3,3-bisubstituted oxindoles with our previously established bifunctional N-acyl aminophosphine catalysts is reported. These products bearing a chiral quaternary carbon center at the C-3 position of the oxindoles may have potential significance in the synthesis of related structures. The best performance of these processes provides adducts with 92% yield and 94% ee. imageWILEY-VCH
Subject Area天然产物有机化学
DOI10.1002/adsc.201300695
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Indexed BySCI
Language英语
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Cited Times:33[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38972
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorCai YP(蔡跃鹏); Zhao G(赵刚)
Affiliation1.华南师范大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Chen JH,Cai YP,Zhao G. Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center[J]. Adv. Synth. Catal.,2014,356(2-3):359-363.
APA 陈锦浩,蔡跃鹏,&赵刚.(2014).Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center.Adv. Synth. Catal.,356(2-3),359-363.
MLA 陈锦浩,et al."Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center".Adv. Synth. Catal. 356.2-3(2014):359-363.
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