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学科主题: 天然产物有机化学
题名: Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
其他题名: Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
作者: Cui Z(崔哲)1; Chen YJ(陈亚静)1; Gao WY(高文运)1; Feng CG(冯陈国)1; Lin GQ(林国强)1
通讯作者: 高文运 ; 冯陈国 ; 林国强
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol5000154
卷: 16, 期:3, 页:1016-1019
收录类别: SCI
英文摘要: An efficient rhodium-catalyzed asymmetric addition reaction of potassium alkenyltrifluoroborates to N-nosylaldimines has been developed. Under optimal conditions, the reactions proceeded with good to excellent yields and excellent enantioselectivities (97 -> 99% ee). The utility of this method is demonstrated by the formal synthesis of (-)-aurantioclavine.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38971
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.西北大学
2.中科院上海有机化学研究所

Recommended Citation:
Cui Z,Chen YJ,Gao WY,et al. Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex[J]. Org. Lett.,2014,16(3):1016-1019.
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