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Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
Alternative TitleEnantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
Cui Z(崔哲)1; Chen YJ(陈亚静)1; Gao WY(高文运)1; Feng CG(冯陈国)1; Lin GQ(林国强)1
2014
Source PublicationOrg. Lett.
Volume16Issue:3Pages:1016-1019
AbstractAn efficient rhodium-catalyzed asymmetric addition reaction of potassium alkenyltrifluoroborates to N-nosylaldimines has been developed. Under optimal conditions, the reactions proceeded with good to excellent yields and excellent enantioselectivities (97 -> 99% ee). The utility of this method is demonstrated by the formal synthesis of (-)-aurantioclavine.
Subject Area天然产物有机化学
DOI10.1021/ol5000154
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Indexed BySCI
Language英语
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Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38971
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorGao WY(高文运); Feng CG(冯陈国); Lin GQ(林国强)
Affiliation1.西北大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Cui Z,Chen YJ,Gao WY,et al. Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex[J]. Org. Lett.,2014,16(3):1016-1019.
APA 崔哲,陈亚静,高文运,冯陈国,&林国强.(2014).Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex.Org. Lett.,16(3),1016-1019.
MLA 崔哲,et al."Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex".Org. Lett. 16.3(2014):1016-1019.
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