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学科主题: 天然产物有机化学
题名: Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
其他题名: Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
作者: Tian B(田兵)1; Liu Q(刘强)1; TONG XIAOFENG1; Tian P(田平)1; Lin GQ(林国强)1
通讯作者: 田平 ; 林国强
刊名: Org. Chem. Front.
发表日期: 2014
DOI: 10.1039/c4qo00157e
卷: 1, 页:1116-112
英文摘要: Copper(I)-catalyzed enantioselective hydroboration of 3-aryl substituted cyclopropene-3-carboxylate is described, providing chiral cyclopropylboronates with excellent enantioselectivities (89–95% ee) in moderate to high yields (55–86%). The non-directing effect of the ester group was observed, and the reaction proceeded with solely trans-selectivity. The chiral boronates could be conveniently converted into chiral 1,2-diaryl substituted cyclopropane derivatives.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38970
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.华东理工大学

Recommended Citation:
Tian B,Liu Q,TONG XIAOFENG,et al. Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates[J]. Org. Chem. Front.,2014,1:1116-112.
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