Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates

doi:10.1039/c4qo00157e

	Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
其他题名	Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
	Tian B(田兵)1; Liu Q(刘强)1; TONG XIAOFENG 1; Tian P(田平)1; Lin GQ(林国强)1
	2014
发表期刊	Org. Chem. Front.
卷号	1 页码:1116-112
摘要	Copper(I)-catalyzed enantioselective hydroboration of 3-aryl substituted cyclopropene-3-carboxylate is described, providing chiral cyclopropylboronates with excellent enantioselectivities (89–95% ee) in moderate to high yields (55–86%). The non-directing effect of the ester group was observed, and the reaction proceeded with solely trans-selectivity. The chiral boronates could be conveniently converted into chiral 1,2-diaryl substituted cyclopropane derivatives.
学科领域	天然产物有机化学
DOI	10.1039/c4qo00157e
URL	查看原文
语种	英语
引用统计	被引频次：19[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sioc.ac.cn/handle/331003/38970
专题	中科院天然产物有机化学重点实验室
通讯作者	Tian P(田平); Lin GQ(林国强)
作者单位	1.中科院上海有机化学研究所 2.华东理工大学
推荐引用方式 GB/T 7714	Tian B,Liu Q,TONG XIAOFENG,et al. Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates[J]. Org. Chem. Front.,2014,1:1116-112.
APA	田兵,刘强,TONG XIAOFENG,田平,&林国强.(2014).Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates.Org. Chem. Front.,1,1116-112.
MLA	田兵,et al."Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates".Org. Chem. Front. 1(2014):1116-112.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
2014038.pdf（1675KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	请求全文