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Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
Alternative TitleCopper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
Tian B(田兵)1; Liu Q(刘强)1; TONG XIAOFENG1; Tian P(田平)1; Lin GQ(林国强)1
2014
Source PublicationOrg. Chem. Front.
Volume1Pages:1116-112
AbstractCopper(I)-catalyzed enantioselective hydroboration of 3-aryl substituted cyclopropene-3-carboxylate is described, providing chiral cyclopropylboronates with excellent enantioselectivities (89–95% ee) in moderate to high yields (55–86%). The non-directing effect of the ester group was observed, and the reaction proceeded with solely trans-selectivity. The chiral boronates could be conveniently converted into chiral 1,2-diaryl substituted cyclopropane derivatives.
Subject Area天然产物有机化学
DOI10.1039/c4qo00157e
URL查看原文
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38970
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorTian P(田平); Lin GQ(林国强)
Affiliation1.中科院上海有机化学研究所
2.华东理工大学
Recommended Citation
GB/T 7714
Tian B,Liu Q,TONG XIAOFENG,et al. Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates[J]. Org. Chem. Front.,2014,1:1116-112.
APA 田兵,刘强,TONG XIAOFENG,田平,&林国强.(2014).Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates.Org. Chem. Front.,1,1116-112.
MLA 田兵,et al."Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates".Org. Chem. Front. 1(2014):1116-112.
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