| Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates | |
| Alternative Title | Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates |
| Tian B(田兵)1; Liu Q(刘强)1; TONG XIAOFENG1; Tian P(田平)1; Lin GQ(林国强)1 | |
| 2014 | |
| Source Publication | Org. Chem. Front.
 |
| Volume | 1Pages:1116-112 |
| Abstract | Copper(I)-catalyzed enantioselective hydroboration of 3-aryl substituted cyclopropene-3-carboxylate is described, providing chiral cyclopropylboronates with excellent enantioselectivities (89–95% ee) in moderate to high yields (55–86%). The non-directing effect of the ester group was observed, and the reaction proceeded with solely trans-selectivity. The chiral boronates could be conveniently converted into chiral 1,2-diaryl substituted cyclopropane derivatives. |
| Subject Area | 天然产物有机化学 |
| DOI | 10.1039/c4qo00157e |
| URL | 查看原文 |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/38970 |
| Collection | 中科院天然产物有机化学重点实验室 |
| Corresponding Author | Tian P(田平); Lin GQ(林国强) |
| Affiliation | 1.中科院上海有机化学研究所 2.华东理工大学 |
| Recommended Citation GB/T 7714 | Tian B,Liu Q,TONG XIAOFENG,et al. Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates[J]. Org. Chem. Front.,2014,1:1116-112. |
| APA | 田兵,刘强,TONG XIAOFENG,田平,&林国强.(2014).Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates.Org. Chem. Front.,1,1116-112. |
| MLA | 田兵,et al."Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates".Org. Chem. Front. 1(2014):1116-112. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2014038.pdf（1675KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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