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Synthesis and Absolute Configurations of Six Natural Phenylpropanoids
其他题名六种苯丙素类化合物的合成及绝对构型确定
Liu XL(刘雪莲)1; Chen HJ(陈慧君)1; Yang YY(杨洋洋)1; Wu YK(伍贻康)1; You J(由君)1
2014
发表期刊Eur. J. Org. Chem.
卷号2014期号:16页码:3451-3459
摘要In an effort to find answers to the tantalizing questions about the absolute configurations of a group of long-known natural phenylpropanoids with very similar structures but different signs for the optical rotations, the compounds in question were synthesized in enantiomerically pure form using Evans asymmetric alkylation to generate the stereogenic centres with predefined absolute configurations. The H-1 and C-13 NMR spectra of the synthetic products were very consistent with those reported for their natural counterparts. In most cases, the optical rotations were also consistent with the corresponding data for the natural samples. The new findings not only allowed unequivocal assignments of the absolute configurations for the natural products, but also revealed that the configurations of closely related compounds from the same plant may be different.
学科领域有机化学
DOI10.1002/ejoc.201402096
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收录类别SCI
语种英语
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38950
专题生命有机化学国家重点实验室
通讯作者Wu YK(伍贻康); You J(由君)
作者单位1.中科院上海有机化学研究所
2.哈尔滨理工大学
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GB/T 7714
Liu XL,Chen HJ,Yang YY,et al. Synthesis and Absolute Configurations of Six Natural Phenylpropanoids[J]. Eur. J. Org. Chem.,2014,2014(16):3451-3459.
APA 刘雪莲,陈慧君,杨洋洋,伍贻康,&由君.(2014).Synthesis and Absolute Configurations of Six Natural Phenylpropanoids.Eur. J. Org. Chem.,2014(16),3451-3459.
MLA 刘雪莲,et al."Synthesis and Absolute Configurations of Six Natural Phenylpropanoids".Eur. J. Org. Chem. 2014.16(2014):3451-3459.
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