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Synthesis and Absolute Configurations of Six Natural Phenylpropanoids
Alternative Title六种苯丙素类化合物的合成及绝对构型确定
Liu XL(刘雪莲)1; Chen HJ(陈慧君)1; Yang YY(杨洋洋)1; Wu YK(伍贻康)1; You J(由君)1
2014
Source PublicationEur. J. Org. Chem.
Volume2014Issue:16Pages:3451-3459
AbstractIn an effort to find answers to the tantalizing questions about the absolute configurations of a group of long-known natural phenylpropanoids with very similar structures but different signs for the optical rotations, the compounds in question were synthesized in enantiomerically pure form using Evans asymmetric alkylation to generate the stereogenic centres with predefined absolute configurations. The H-1 and C-13 NMR spectra of the synthetic products were very consistent with those reported for their natural counterparts. In most cases, the optical rotations were also consistent with the corresponding data for the natural samples. The new findings not only allowed unequivocal assignments of the absolute configurations for the natural products, but also revealed that the configurations of closely related compounds from the same plant may be different.
Subject Area有机化学
DOI10.1002/ejoc.201402096
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38950
Collection生命有机化学国家重点实验室
Corresponding AuthorWu YK(伍贻康); You J(由君)
Affiliation1.中科院上海有机化学研究所
2.哈尔滨理工大学
Recommended Citation
GB/T 7714
Liu XL,Chen HJ,Yang YY,et al. Synthesis and Absolute Configurations of Six Natural Phenylpropanoids[J]. Eur. J. Org. Chem.,2014,2014(16):3451-3459.
APA 刘雪莲,陈慧君,杨洋洋,伍贻康,&由君.(2014).Synthesis and Absolute Configurations of Six Natural Phenylpropanoids.Eur. J. Org. Chem.,2014(16),3451-3459.
MLA 刘雪莲,et al."Synthesis and Absolute Configurations of Six Natural Phenylpropanoids".Eur. J. Org. Chem. 2014.16(2014):3451-3459.
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