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Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products
Alternative TitleRecent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products
Wan CY(万春云)1; Deng J(邓军)1; Liu H(刘华)1; Bian M(卞明)1; Li A(李昂)1
2014
Source PublicationSci. China-Chem.
Volume57Issue:7Pages:926-929
AbstractThe Diels-Alder (D-A) reaction is one of the most powerful reactions in organic synthesis. The intermolecular D-A reaction attracts much less attentions than its intramolecular counterpart in natural product synthesis, possibly due to the issues of reactivity and selectivity. In the past decade, the intermolecular D-A reaction has been increasingly utilized in the total synthesis of structurally complex natural products. In this article, we present a few examples for the elegant applications of the intermolecular D-A reaction that are inspired by biosynthetic hypotheses of the target natural products. These examples demonstrate that D-A reaction is not only useful for preparing building blocks but also powerful for coupling structurally complicated and sterically demanding segments in a highly chemo- and stereo-controlled fashion, which may inspire further developments of intermolecular D-A reaction from both strategy and methodology perspectives.
Subject Area生命有机化学
DOI10.1007/s11426-014-5144-5
URL查看原文
Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38947
Collection生命有机化学国家重点实验室
Corresponding AuthorLi A(李昂)
Affiliation1.江西中医药大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Wan CY,Deng J,Liu H,et al. Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products[J]. Sci. China-Chem.,2014,57(7):926-929.
APA 万春云,邓军,刘华,卞明,&李昂.(2014).Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products.Sci. China-Chem.,57(7),926-929.
MLA 万春云,et al."Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products".Sci. China-Chem. 57.7(2014):926-929.
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