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学科主题: 生命有机化学
题名: Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products
其他题名: Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products
作者: Wan CY(万春云)1; Deng J(邓军)1; Liu H(刘华)1; Bian M(卞明)1; Li A(李昂)1
通讯作者: 李昂
刊名: Sci. China-Chem.
发表日期: 2014
DOI: 10.1007/s11426-014-5144-5
卷: 57, 期:7, 页:926-929
收录类别: SCI
英文摘要: The Diels-Alder (D-A) reaction is one of the most powerful reactions in organic synthesis. The intermolecular D-A reaction attracts much less attentions than its intramolecular counterpart in natural product synthesis, possibly due to the issues of reactivity and selectivity. In the past decade, the intermolecular D-A reaction has been increasingly utilized in the total synthesis of structurally complex natural products. In this article, we present a few examples for the elegant applications of the intermolecular D-A reaction that are inspired by biosynthetic hypotheses of the target natural products. These examples demonstrate that D-A reaction is not only useful for preparing building blocks but also powerful for coupling structurally complicated and sterically demanding segments in a highly chemo- and stereo-controlled fashion, which may inspire further developments of intermolecular D-A reaction from both strategy and methodology perspectives.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38947
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.江西中医药大学
2.中科院上海有机化学研究所

Recommended Citation:
Wan CY,Deng J,Liu H,et al. Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products[J]. Sci. China-Chem.,2014,57(7):926-929.
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