中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 生命有机化学国家重点实验室  > 期刊论文
学科主题: 生命有机化学
题名: Synthesis of a vinylchlorine-containing 1,3-diol from a marine cyanophyte
其他题名: 由海洋蓝藻分离得到的含有烯基氯的1,3-二醇的合成
作者: Wang XL(王晓龙)1; Yang YY(杨洋洋)1; Chen HJ(陈慧君)1; Wu YK(伍贻康)1; Ma DS(马东升)1
通讯作者: 伍贻康 ; 马东升
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.04.090
卷: 70, 期:30, 页:4571-4579
收录类别: SCI
英文摘要: Using epoxy chiral building blocks readily derived from D-gluconolactone as the source of the stereogenic centers, both (6R,8R)- and (6R,8S)-isomers of (E)-1-chlorotridec-1-ene-6,8-diol were synthesized. The vinylchloro unit was installed onto the substrate carbon chain in an approximately 9:1 (E)/(Z) ratio via a condensation of CrCl2/CHCl3 with a terminal aldehyde. A tosylation protocol featuring addition of H2O was also developed for a highly polar tetraol. The synthetic products allowed for re-acquisition of the NMR spectra of better quality and revealed some delicate yet unignorable discrepancies in the C-13 NMR for the natural isomer obtained by synthesis and that isolated some 30 years ago from the marine cyanophyte. The puzzling discrepancies were eventually shown to be caused by deuteration of the hydroxyl groups. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38946
Appears in Collections:生命有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2014276.pdf(489KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.黑龙江大学
2.中科院上海有机化学研究所

Recommended Citation:
Wang XL,Yang YY,Chen HJ,et al. Synthesis of a vinylchlorine-containing 1,3-diol from a marine cyanophyte[J]. Tetrahedron,2014,70(30):4571-4579.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[王晓龙]'s Articles
[杨洋洋]'s Articles
[陈慧君]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[王晓龙]‘s Articles
[杨洋洋]‘s Articles
[陈慧君]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2014276.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace