中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 生命有机化学国家重点实验室  > 期刊论文
学科主题: 生命有机化学
题名: Copper-catalyzed coupling of aryl iodides and tert-butyl beta-keto esters: efficient access to alpha-aryl ketones and alpha-arylacetic acid tert-butyl esters
其他题名: 铜催化的芳基碘代物与 b-酮基叔丁酯的偶联反应: 有效合成a-芳基酮和a-芳基乙酸叔丁酯
作者: Zhao D(赵铎); Jiang YW(蒋咏文); Ma DW(马大为)
通讯作者: 马大为
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet2013.10.017
卷: 70, 期:20, 页:3327-3332
收录类别: SCI
英文摘要: CuI/trans-4-hydroxy-t-proline catalyzed coupling of aryl iodides with tert-butyl beta-keto esters proceeded smoothly at 40 degrees C in DMF, providing alpha-aryl ketones after acid-promoted deprotection and decarboxylation of tert-butyl ester group. While CuI/2-picolinic acid catalyzed coupling of aryl iodides with tert-butyl acetoacetate at 70 degrees C in dioxane delivered alpha-arylacetic acid tert-butyl esters upon spontaneous deacylation. A wide range of functional groups, such as acetyl, methoxy, nitrile, nitro, bromo, and chloro were compatible with the reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38944
Appears in Collections:生命有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2014225.pdf(635KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhao D,Jiang YW,Ma DW. Copper-catalyzed coupling of aryl iodides and tert-butyl beta-keto esters: efficient access to alpha-aryl ketones and alpha-arylacetic acid tert-butyl esters[J]. Tetrahedron,2014,70(20):3327-3332.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[赵铎]'s Articles
[蒋咏文]'s Articles
[马大为]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[赵铎]‘s Articles
[蒋咏文]‘s Articles
[马大为]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2014225.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace