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学科主题: 生命有机化学
题名: A copper-catalyzed coupling reaction of vinyl halides and carbazates: application in the assembly of polysubstituted pyrroles
其他题名: 铜催化的烯基卤代物与肼衍生物的偶联反应: 应用于合成多取代的吡咯衍生物
作者: Zou CG(邹成刚)1; Ma DW(马大为)1
通讯作者: 马大为
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c3cc49724k
卷: 50, 期:23, 页:3085-3088
收录类别: SCI
英文摘要: CuI-catalyzed coupling of vinyl halides with carbazates gives N-protected N-alkenylhydrazines, which are condensed with ketones under acidic conditions to give polysubstituted pyrroles. The pyrrole synthesis may go through a similar mechanism with Fischer indole synthesis, which involves a [3,3]-sigmatropic rearrangement and other reactions.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38935
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.罗氏药物研发(中国)中心
3.中科院上海有机化学研究所

Recommended Citation:
Zou CG,Ma DW. A copper-catalyzed coupling reaction of vinyl halides and carbazates: application in the assembly of polysubstituted pyrroles[J]. Chem. Commun.,2014,50(23):3085-3088.
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