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学科主题: 生命有机化学
题名: Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta
其他题名: 由香芋Colocasia antiquorum var. esculenta变种块茎皮分离得到的具抗增色作用的甘油脂肪酸酯的合成
作者: Zhu SJ(朱时俊); Wu YK(伍贻康)
通讯作者: 伍贻康
刊名: Synlett
发表日期: 2014
DOI: 10.1055/s-0033-1340078
卷: 25, 期:2, 页:261-264
收录类别: SCI
英文摘要: (2S)-1-O-9-Oxo-(10E,12E)-octadecadienoyl glycerol, a natural anti-melanogenic monoglyceride, is synthesized for the first time. The chiral pool based route employed not only confirms the absolute configuration, but also illustrates the first synthetic entry to the (E,E)-diene keto acid, which is another molecule of biological importance. The confusion caused by the misinterpreted H-1 NMR spectroscopic data for the (E,E)-diene motif in the literature is discussed. The first unequivocal piece of evidence for the assigned (12E) configuration is also presented.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38931
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhu SJ,Wu YK. Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta[J]. Synlett,2014,25(2):261-264.
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