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Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta
Alternative Title由香芋Colocasia antiquorum var. esculenta变种块茎皮分离得到的具抗增色作用的甘油脂肪酸酯的合成
Zhu SJ(朱时俊); Wu YK(伍贻康)
2014
Source PublicationSynlett
Volume25Issue:2Pages:261-264
Abstract(2S)-1-O-9-Oxo-(10E,12E)-octadecadienoyl glycerol, a natural anti-melanogenic monoglyceride, is synthesized for the first time. The chiral pool based route employed not only confirms the absolute configuration, but also illustrates the first synthetic entry to the (E,E)-diene keto acid, which is another molecule of biological importance. The confusion caused by the misinterpreted H-1 NMR spectroscopic data for the (E,E)-diene motif in the literature is discussed. The first unequivocal piece of evidence for the assigned (12E) configuration is also presented.
Subject Area生命有机化学
DOI10.1055/s-0033-1340078
URL查看原文
Indexed BySCI
Language英语
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Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38931
Collection生命有机化学国家重点实验室
Corresponding AuthorWu YK(伍贻康)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhu SJ,Wu YK. Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta[J]. Synlett,2014,25(2):261-264.
APA 朱时俊,&伍贻康.(2014).Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta.Synlett,25(2),261-264.
MLA 朱时俊,et al."Synthesis of the Anti-Melanogenic Glycerol Fatty Acid Ester Isolated from the Tuber-Barks of Colocasia antiquorum var. esculenta".Synlett 25.2(2014):261-264.
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