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Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis
其他题名非洲加蓬盘豆木分离得到的甘油酯Hylodiglyceride的合成及构型确定
Wu WJ(武文菊)1; Chen HJ(陈慧君)1; Wu YK(伍贻康)1; Liu B(刘波)1
2014
发表期刊Tetrahedron
卷号70期号:1页码:92-96
摘要A recently isolated bismonoglyceride of heptadecanedioic acid, which represents a novel type of natural monoglycerides (i.e., with two instead of only one glycerol unit in the molecular architecture), was synthesized in enantiopure forms using a chiral-pool based approach with the 17-carbon chain constructed from undec-10-enoic acid and oct-7-en-1-ol via a cross metathesis and the stereogenic centers derived from (R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methanol. An analogue with a longer alkyl chain was also synthesized. The synthetic samples not only allowed for establishment of the absolute configuration but also helped to reveal some minor yet unignorable errors in the H-1 NMR data for the natural product. Optical rotation and NMR data acquired in DMSO and DMSO-d(6), respectively, are also presented. (C) 2013 Elsevier Ltd. All rights reserved.
学科领域生命有机化学
DOI10.1016/j.tet.2013.11.021
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收录类别SCI
语种英语
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38930
专题生命有机化学国家重点实验室
通讯作者Wu YK(伍贻康); Liu B(刘波)
作者单位1.哈尔滨理工大学
2.中科院上海有机化学研究所
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GB/T 7714
Wu WJ,Chen HJ,Wu YK,et al. Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis[J]. Tetrahedron,2014,70(1):92-96.
APA 武文菊,陈慧君,伍贻康,&刘波.(2014).Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis.Tetrahedron,70(1),92-96.
MLA 武文菊,et al."Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis".Tetrahedron 70.1(2014):92-96.
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