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学科主题: 生命有机化学
题名: Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis
其他题名: 非洲加蓬盘豆木分离得到的甘油酯Hylodiglyceride的合成及构型确定
作者: Wu WJ(武文菊)1; Chen HJ(陈慧君)1; Wu YK(伍贻康)1; Liu B(刘波)1
通讯作者: 伍贻康 ; 刘波
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2013.11.021
卷: 70, 期:1, 页:92-96
收录类别: SCI
英文摘要: A recently isolated bismonoglyceride of heptadecanedioic acid, which represents a novel type of natural monoglycerides (i.e., with two instead of only one glycerol unit in the molecular architecture), was synthesized in enantiopure forms using a chiral-pool based approach with the 17-carbon chain constructed from undec-10-enoic acid and oct-7-en-1-ol via a cross metathesis and the stereogenic centers derived from (R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methanol. An analogue with a longer alkyl chain was also synthesized. The synthetic samples not only allowed for establishment of the absolute configuration but also helped to reveal some minor yet unignorable errors in the H-1 NMR data for the natural product. Optical rotation and NMR data acquired in DMSO and DMSO-d(6), respectively, are also presented. (C) 2013 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38930
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.哈尔滨理工大学
2.中科院上海有机化学研究所

Recommended Citation:
Wu WJ,Chen HJ,Wu YK,et al. Synthesis and absolute configuration of hylodiglyceride isolated from Hylodendron gabunensis[J]. Tetrahedron,2014,70(1):92-96.
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