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学科主题: 生命有机化学
题名: Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A
其他题名: 吲哚单萜生物碱aspidophylline A的全合成
作者: Teng MX(滕明星); Zi WW(资伟伟); Ma DW(马大为)
通讯作者: 马大为
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201310928
卷: 53, 期:7, 页:1814-1817
收录类别: SCI
英文摘要: AspidophyllineA belongs to the akuammiline alkaloid family, the members of which possess intriguing cagelike structures and diverse biological activities. Herein we report a 15-step synthesis of this alkaloid from conveniently available starting materials. The key elements of the synthesis include an intramolecular oxidative coupling to create the tetracyclic furoindoline motif of the natural product and a [Ni(cod)(2)]-mediated cyclization to install its piperidine ring.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38928
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Teng MX,Zi WW,Ma DW. Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A[J]. Angew. Chem.-Int. Edit.,2014,53(7):1814-1817.
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