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Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A
Alternative Title吲哚单萜生物碱aspidophylline A的全合成
Teng MX(滕明星); Zi WW(资伟伟); Ma DW(马大为)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:7Pages:1814-1817
AbstractAspidophyllineA belongs to the akuammiline alkaloid family, the members of which possess intriguing cagelike structures and diverse biological activities. Herein we report a 15-step synthesis of this alkaloid from conveniently available starting materials. The key elements of the synthesis include an intramolecular oxidative coupling to create the tetracyclic furoindoline motif of the natural product and a [Ni(cod)(2)]-mediated cyclization to install its piperidine ring.
Subject Area生命有机化学
DOI10.1002/anie.201310928
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Indexed BySCI
Language英语
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Cited Times:67[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38928
Collection生命有机化学国家重点实验室
Corresponding AuthorMa DW(马大为)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Teng MX,Zi WW,Ma DW. Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A[J]. Angew. Chem.-Int. Edit.,2014,53(7):1814-1817.
APA 滕明星,资伟伟,&马大为.(2014).Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A.Angew. Chem.-Int. Edit.,53(7),1814-1817.
MLA 滕明星,et al."Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A".Angew. Chem.-Int. Edit. 53.7(2014):1814-1817.
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