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Fluorinated poly(meth)acrylate: Synthesis and properties
Alternative TitleFluorinated poly(meth)acrylate: Synthesis and properties
Yao WQ(姚文强); Li YJ(李永军); Huang XY(黄晓宇)
Source PublicationPolymer
AbstractDue to good reactivity of fluorinated (meth)acrylates with other monomers or polymer segments, fluorinated poly(meth)acrylates possess more economical and convenient synthesis routes than other fluoropolymers. This feature article initially summarizes different types of fluorinated (meth)acrylates, which can be divided into fluorinated alkyl (meth)acrylates and fluorinated aryl (meth)acrylates. Subsequently, various approaches for synthesizing fluorinated poly(meth)acrylates including random, block, graft or star copolymers are described. Conventional free radical polymerization can be used in synthesizing random copolymers, while controlled/"living" radical polymerization can provide well-defined copolymers with accurate control over molecular weight and special structures as expected. In particular, introduction of fluorinated components into as-prepared copolymers offers an alternative route to synthesize fluorinated poly(meth)acrylates which are difficult to be obtained directly via polymerization. The incorporation of fluorine can confer unique and highly desirable properties to poly(meth)acrylates such as low surface energy, thermal stability, chemical and weather resistance, low refractive index, and self-organization characteristics. Such properties are described in great details based on many recent articles. (C) 2014 Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.
Subject Area高分子化学
Indexed BySCI
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Document Type期刊论文
Corresponding AuthorLi YJ(李永军); Huang XY(黄晓宇)
Recommended Citation
GB/T 7714
Yao WQ,Li YJ,Huang XY. Fluorinated poly(meth)acrylate: Synthesis and properties[J]. Polymer,2014,55(24):6197-6211.
APA 姚文强,李永军,&黄晓宇.(2014).Fluorinated poly(meth)acrylate: Synthesis and properties.Polymer,55(24),6197-6211.
MLA 姚文强,et al."Fluorinated poly(meth)acrylate: Synthesis and properties".Polymer 55.24(2014):6197-6211.
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