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学科主题: 高分子化学
题名: Fluorinated poly(meth)acrylate: Synthesis and properties
其他题名: Fluorinated poly(meth)acrylate: Synthesis and properties
作者: Yao WQ(姚文强); Li YJ(李永军); Huang XY(黄晓宇)
通讯作者: 李永军 ; 黄晓宇
刊名: Polymer
发表日期: 2014
DOI: 10.1016/j.polymer.2014.09.036
卷: 55, 期:24, 页:6197-6211
收录类别: SCI
英文摘要: Due to good reactivity of fluorinated (meth)acrylates with other monomers or polymer segments, fluorinated poly(meth)acrylates possess more economical and convenient synthesis routes than other fluoropolymers. This feature article initially summarizes different types of fluorinated (meth)acrylates, which can be divided into fluorinated alkyl (meth)acrylates and fluorinated aryl (meth)acrylates. Subsequently, various approaches for synthesizing fluorinated poly(meth)acrylates including random, block, graft or star copolymers are described. Conventional free radical polymerization can be used in synthesizing random copolymers, while controlled/"living" radical polymerization can provide well-defined copolymers with accurate control over molecular weight and special structures as expected. In particular, introduction of fluorinated components into as-prepared copolymers offers an alternative route to synthesize fluorinated poly(meth)acrylates which are difficult to be obtained directly via polymerization. The incorporation of fluorine can confer unique and highly desirable properties to poly(meth)acrylates such as low surface energy, thermal stability, chemical and weather resistance, low refractive index, and self-organization characteristics. Such properties are described in great details based on many recent articles. (C) 2014 Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38914
Appears in Collections:高分子材料研究室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Yao WQ,Li YJ,Huang XY. Fluorinated poly(meth)acrylate: Synthesis and properties[J]. Polymer,2014,55(24):6197-6211.
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