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学科主题: 氟化学
题名: Heteroaryldifluoromethylation of Organoborons Catalyzed by Palladium: Facile Access to Aryl(Heteroaryl)difluoromethanes
其他题名: 一种简便合成芳基(杂芳基)二氟甲烷的方法: 有机硼的杂芳基二氟甲基化
作者: Xiao YL(肖玉兰); Zhang B(章博); Feng Z(冯璋); Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol502121m
卷: 16, 期:18, 页:4822-4825
收录类别: SCI
英文摘要: A first example of Pd-catalyzed heteroaryldifluoromethylation of organoborons with bromodifluoromethylated heteroarenes has been described. The use of phosphine ligand PAd(2)(n-Bu)center dot HI is critical for the reaction efficiency. With use of this ligand, a wide range of aryl(heteroaryl)difluoromethanes were obtained with high efficiency. The notable features of this reaction are its broad substrate scope and excellent functional group compatibility, thus providing a facile protocol for application in drug discovery and development.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38881
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Xiao YL,Zhang B,Feng Z,et al. Heteroaryldifluoromethylation of Organoborons Catalyzed by Palladium: Facile Access to Aryl(Heteroaryl)difluoromethanes[J]. Org. Lett.,2014,16(18):4822-4825.
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