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学科主题: 氟化学
题名: Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium
其他题名: 钯催化下溴二氟丙烯对有机硼试剂的高选择性偕二氟烯丙基化
作者: Min QQ(闵巧桥); Yin ZS(尹增升); Feng Z(冯璋); Guo WH(郭文豪); Zhang XG(张新刚)
通讯作者: 张新刚
刊名: J. Am. Chem. Soc.
发表日期: 2014
DOI: 10.1021/ja4114825
卷: 136, 期:4, 页:1230-1233
收录类别: SCI
英文摘要: A first example of Pd-catalyzed gem-difluoroallylation of organoborons using 3-bromo-3,3-difluoropropene (BDFP) in high efficiency with high alpha/gamma-substitution regioselectivity has been developed. The reaction can also be extended to substituted BDFPs and has advantages of low catalyst loading (0.8 to 0.01 mol %), broad substrate scope, and excellent functional group compatibility, thus providing a facile route for practical application in drug discovery and development.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38875
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Min QQ,Yin ZS,Feng Z,et al. Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium[J]. J. Am. Chem. Soc.,2014,136(4):1230-1233.
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