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学科主题: 氟化学
题名: Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis
其他题名: 不对称有机催化氟化与氟烷基化反应研究进展
作者: Lin JH(林锦鸿); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Tetrahedron Lett.
发表日期: 2014
DOI: 10.1016/j.tetlet.2014.09.031
卷: 55, 期:45, 页:6147-6155
收录类别: SCI
英文摘要: The past decade has witnessed the significant advances of asymmetric organocatalytic fluorination, monofluoroalkylation, gem-difluoroalkylation, and trifluoromethylation. This digest summarizes the latest progress of these reactions. In the research area of asymmetric organocatalytic fluorination, a new catalysis concept, chiral anion phase-transfer catalysis strategy, has emerged and has proved to be highly efficient. Asymmetric organocatalytic monofluoroalkylation and gem-difluoroalkylation have been much less explored and the Lewis base/acid catalysis has been the most used strategy. Compared with electrophilic trifluoromethylation, nucleophilic trifluoromethylation has been intensively studied in the research field of asymmetric organocatalytic trifluoromethylation. (C) 2014 Published by Elsevier Ltd.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38870
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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Lin JH,Xiao JC. Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis[J]. Tetrahedron Lett.,2014,55(45):6147-6155.
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