中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: Cu-Promoted Oxidative Trifluoromethylation of Terminal Alkynes with Difluoromethylene Phosphobetaine
其他题名: 铜粉促进下二氟甲基鏻内盐对末端炔烃的氧化三氟甲基化
作者: Deng XY(邓晓云); Lin JH(林锦鸿); Zheng J(郑剑); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chin. J. Chem.
发表日期: 2014
DOI: 10.1002/cjoc.201400427
卷: 32, 期:8, 页:689-693
收录类别: SCI
英文摘要: Difluoromethylene phosphobetaine (Ph3P+CF2CO2-, PDFA), a known difluorocarbene reagent, was found to be able to efficiently trifluoromethylate terminal alkynes in the presence of Cu(I) and potassium fluoride. The transformation proceeded smoothly to afford the corresponding trifluoromethylated acetylenes in moderate yields.
语种: 英语
相关网址: 查看原文
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38869
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2014437.pdf(337KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所

Recommended Citation:
Deng XY,Lin JH,Zheng J,et al. Cu-Promoted Oxidative Trifluoromethylation of Terminal Alkynes with Difluoromethylene Phosphobetaine[J]. Chin. J. Chem.,2014,32(8):689-693.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[邓晓云]'s Articles
[林锦鸿]'s Articles
[郑剑]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[邓晓云]‘s Articles
[林锦鸿]‘s Articles
[郑剑]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2014437.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace