SIOC OpenIR  > 中科院有机氟化学重点实验室
Decarboxylative Julia- Kocienski gem- Difluoro- Olefination of 2-Pyridinyl Sulfonyldifluoroacetate
Alternative Title2-吡啶砜基二氟乙酸盐的脱羧Julia–Kocienski二氟烯基化
Wang XP(王小平)1; Lin JH(林锦鸿)1; Xiao JC(肖吉昌)1; Zheng X(郑兴)1
Source PublicationEur. J. Org. Chem.
AbstractThe decarboxylation of potassium 2-pyridinyl sulfonyldifluoroacetate and its subsequent reaction with aldehydes was found to be an efficient approach for the Julia-Kocienski reaction under mild conditions to give gem-difluoro olefins in moderate to excellent yields. Owing to its high stability in the pure state and its easy decarboxylation in polar solvents, potassium 2-pyridinyl sulfonyldifluoroacetate is expected to be an efficient gem-difluoro-olefination reagent.
Subject Area氟化学
Indexed BySCI
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorXiao JC(肖吉昌)
Recommended Citation
GB/T 7714
Wang XP,Lin JH,Xiao JC,et al. Decarboxylative Julia- Kocienski gem- Difluoro- Olefination of 2-Pyridinyl Sulfonyldifluoroacetate[J]. Eur. J. Org. Chem.,2014,2014(5):928-932.
APA 王小平,林锦鸿,肖吉昌,&郑兴.(2014).Decarboxylative Julia- Kocienski gem- Difluoro- Olefination of 2-Pyridinyl Sulfonyldifluoroacetate.Eur. J. Org. Chem.,2014(5),928-932.
MLA 王小平,et al."Decarboxylative Julia- Kocienski gem- Difluoro- Olefination of 2-Pyridinyl Sulfonyldifluoroacetate".Eur. J. Org. Chem. 2014.5(2014):928-932.
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