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学科主题: 氟化学
题名: Rh-catalyzed allylic C-F bond activation: the stereoselective synthesis of trisubstituted monofluoroalkenes and a mechanism study
其他题名: 铑催化的烯丙位碳氟键活化: 三取代单氟烯烃的合成与机理
作者: Zhang H(张禾)1; Lin JH(林锦鸿)1; Xiao JC(肖吉昌)1; Gu YC(顾玉诚)1
通讯作者: 肖吉昌
刊名: Org. Biomol. Chem.
发表日期: 2014
DOI: 10.1039/c3ob42038h
卷: 12, 期:4, 页:581-588
收录类别: SCI
英文摘要: Rhodium-catalyzed allylic C-F bond activation via oxidative addition was found to be a promising approach for the conversion of allylic difluoro-homoallylic alcohols into trisubstituted monofluoroalkenes in good yields with excellent stereoselectivity. The mechanism study shows that C-F bond activation via oxidative addition is involved and PPh3 is responsible for the excellent stereoselectivity.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38862
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中国科学院上海有机化学研究所, 有机氟化学重点实验室
2.英国Syngenta

Recommended Citation:
Zhang H,Lin JH,Xiao JC,et al. Rh-catalyzed allylic C-F bond activation: the stereoselective synthesis of trisubstituted monofluoroalkenes and a mechanism study[J]. Org. Biomol. Chem.,2014,12(4):581-588.
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