SIOC OpenIR  > 中科院有机氟化学重点实验室
Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones
Alternative Title三卤化硼作用下二氟环丙基酮的区域选择性开环反应
Yang TP(杨唐婆); Li Q(李强); Lin JH(林锦鸿); Xiao JC(肖吉昌)
2014
Source PublicationChem. Commun.
Volume50Issue:9Pages:1077-1079
AbstractBoron trihalide-promoted ring-opening reactions of gem-difluorocyclopropyl ketones to give the corresponding beta-trifluoromethyl ketones and beta-halodifluoromethyl ketones were described. It was found that boron trihalides act as both Lewis acids and nucleophiles and the proximal bond prefers to cleave in this transformation.
Subject Area氟化学
DOI10.1039/c3cc47879c
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Indexed BySCI
Language英语
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Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38861
Collection中科院有机氟化学重点实验室
Corresponding AuthorXiao JC(肖吉昌)
Affiliation中国科学院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Yang TP,Li Q,Lin JH,et al. Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones[J]. Chem. Commun.,2014,50(9):1077-1079.
APA 杨唐婆,李强,林锦鸿,&肖吉昌.(2014).Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones.Chem. Commun.,50(9),1077-1079.
MLA 杨唐婆,et al."Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones".Chem. Commun. 50.9(2014):1077-1079.
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