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学科主题: 氟化学
题名: Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones
其他题名: 三卤化硼作用下二氟环丙基酮的区域选择性开环反应
作者: Yang TP(杨唐婆); Li Q(李强); Lin JH(林锦鸿); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c3cc47879c
卷: 50, 期:9, 页:1077-1079
收录类别: SCI
英文摘要: Boron trihalide-promoted ring-opening reactions of gem-difluorocyclopropyl ketones to give the corresponding beta-trifluoromethyl ketones and beta-halodifluoromethyl ketones were described. It was found that boron trihalides act as both Lewis acids and nucleophiles and the proximal bond prefers to cleave in this transformation.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38861
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中国科学院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Yang TP,Li Q,Lin JH,et al. Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones[J]. Chem. Commun.,2014,50(9):1077-1079.
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