SIOC OpenIR  > 中科院有机氟化学重点实验室
Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning
Alternative Title氟化石墨烯: 便利的溶液合成法和氟含量对性能的调控
Zhao FG(赵福刚)1; Zhao G(赵刚)1; Liu XH(刘新华)1; Ge CW(葛从伍)1; Wang JT(王金土)1; Li BL(李柏力)1; Wang QG(王启刚)1; Li WS(李维实)1; Chen QY(陈庆云)1
2014
Source PublicationJ. Mater. Chem. A
Volume2Issue:23Pages:8782-8789
AbstractFluorinated graphene is one of the most important two-dimensional carbon nanomaterials derived from graphene, and possesses specific and outstanding properties. However, it lacks a cost-effective and large-scale preparation method. Here, we describe a novel and facile solution approach using graphene oxide (GO) and liquid diethylaminosulfur trifluoride as starting materials under mild conditions. The chemical composition and the structure of so-prepared fluorinated graphene were characterized in detail by elemental analysis, solid state F-19 NMR, XPS, FT-IR, Raman, SEM, TEM, and AFM. These studies reveal that some oxygen-containing moieties in GO are converted into C-F bonds, while some are eliminated during the reaction. More interestingly, the fluorine-loading amount can be well tuned by simply altering the reaction medium, and has a significant impact on the optical, electronic, and conductive properties of the product. Preliminary experiments on its application as an electrode material for solid-state supercapacitors were finally presented.
Subject Area氟化学 ; 高分子化学
DOI10.1039/c4ta00847b
URL查看原文
Indexed BySCI
Language英语
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38860
Collection中科院有机氟化学重点实验室
Corresponding AuthorWang QG(王启刚); Li WS(李维实); Chen QY(陈庆云)
Affiliation1.中科院上海有机化学研究所
2.同济大学
Recommended Citation
GB/T 7714
Zhao FG,Zhao G,Liu XH,et al. Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning[J]. J. Mater. Chem. A,2014,2(23):8782-8789.
APA 赵福刚.,赵刚.,刘新华.,葛从伍.,王金土.,...&陈庆云.(2014).Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning.J. Mater. Chem. A,2(23),8782-8789.
MLA 赵福刚,et al."Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning".J. Mater. Chem. A 2.23(2014):8782-8789.
Files in This Item:
File Name/Size DocType Version Access License
2014273.pdf(1133KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[赵福刚]'s Articles
[赵刚]'s Articles
[刘新华]'s Articles
Baidu academic
Similar articles in Baidu academic
[赵福刚]'s Articles
[赵刚]'s Articles
[刘新华]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[赵福刚]'s Articles
[赵刚]'s Articles
[刘新华]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.