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学科主题: 氟化学
题名: Nickel-Catalyzed alpha-Arylation of Zinc Enolates with Polyfluoroarenes via C-F Bond Activation under Neutral Conditions
其他题名: 镍催化的中性条件下锌试剂与多氟芳烃经碳氟键活化的偶联反应研究
作者: Yu DH(于道鸿)1; Wang CS(王昌盛)1; Yao C(姚成)1; Shen QL(沈其龙)1; Lv L(吕龙)1
通讯作者: 沈其龙 ; 吕龙
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol502499q
卷: 16, 期:21, 页:5544-5547
收录类别: SCI
英文摘要: The first nickel-catalyzed alpha-arylation of 2-(polyfluorophenyl) pyridine with zinc enolates of esters or amides via C-F bond activation under neutral conditions is described. A variety of functional groups such as ester, amide, ether, and amine were tolerated. This method provides a simple and useful tool to synthesize fluorinated a-aryl carboxylic acids and a-aryl amides that are important intermediates for drug discovery
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38859
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.南京工业大学

Recommended Citation:
Yu DH,Wang CS,Yao C,et al. Nickel-Catalyzed alpha-Arylation of Zinc Enolates with Polyfluoroarenes via C-F Bond Activation under Neutral Conditions[J]. Org. Lett.,2014,16(21):5544-5547.
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