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学科主题: 氟化学
题名: N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent
其他题名: 糖精衍生的三氟甲硫基试剂: 一种易合成、稳定、适用范围广的亲电三氟甲硫基试剂
作者: Xu CF(徐春发); Ma BQ(马冰清); Shen QL(沈其龙)
通讯作者: 沈其龙
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201403983
卷: 53, 期:35, 页:9316-9320
收录类别: SCI
英文摘要: A new, electrophilic trifluoromethylthiolating reagent, N-trifluoromethylthiosaccharin, was developed and can be synthesized in two steps from saccharin within 30 minutes. N-trifluoromethylthiosaccharin is a powerful trifluoromethylthiolating reagent and allows the trifluoromethylthiolation of a variety of nucleophiles such as alcohols, amines, thiols, electron-rich arenes, aldehydes, ketones, acyclic beta-ketoesters, and alkynes under mild reaction conditions.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38856
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Xu CF,Ma BQ,Shen QL. N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent[J]. Angew. Chem.-Int. Edit.,2014,53(35):9316-9320.
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