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Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion
其他题名银催化的脂肪酸乳液相脱羧三氟甲硫基化反应研究
Hu F(胡峰); Shao XX(邵欣欣); Zhu DH(朱佃虎); Lv L(吕龙); Shen QL(沈其龙)
2014
发表期刊Angew. Chem.-Int. Edit.
卷号53期号:24页码:6105-6109
摘要A silver-catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of functional groups. The reaction was dramatically accelerated by its performance in an aqueous emulsion, which was formed by the addition of sodium dodecyl sulfate to water. It was proposed that the radical, which was generated from the silver-catalyzed decarboxylation in the "oil-in-water" droplets, could easily react with the trifluoromethylthiolating reagent to form the product.
学科领域氟化学
DOI10.1002/anie.201402573
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收录类别SCI
语种英语
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38855
专题中科院有机氟化学重点实验室
通讯作者Shen QL(沈其龙)
作者单位中科院上海有机化学研究所
推荐引用方式
GB/T 7714
Hu F,Shao XX,Zhu DH,et al. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion[J]. Angew. Chem.-Int. Edit.,2014,53(24):6105-6109.
APA 胡峰,邵欣欣,朱佃虎,吕龙,&沈其龙.(2014).Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion.Angew. Chem.-Int. Edit.,53(24),6105-6109.
MLA 胡峰,et al."Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion".Angew. Chem.-Int. Edit. 53.24(2014):6105-6109.
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