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Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion
Alternative Title银催化的脂肪酸乳液相脱羧三氟甲硫基化反应研究
Hu F(胡峰); Shao XX(邵欣欣); Zhu DH(朱佃虎); Lv L(吕龙); Shen QL(沈其龙)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:24Pages:6105-6109
AbstractA silver-catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of functional groups. The reaction was dramatically accelerated by its performance in an aqueous emulsion, which was formed by the addition of sodium dodecyl sulfate to water. It was proposed that the radical, which was generated from the silver-catalyzed decarboxylation in the "oil-in-water" droplets, could easily react with the trifluoromethylthiolating reagent to form the product.
Subject Area氟化学
DOI10.1002/anie.201402573
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38855
Collection中科院有机氟化学重点实验室
Corresponding AuthorShen QL(沈其龙)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Hu F,Shao XX,Zhu DH,et al. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion[J]. Angew. Chem.-Int. Edit.,2014,53(24):6105-6109.
APA 胡峰,邵欣欣,朱佃虎,吕龙,&沈其龙.(2014).Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion.Angew. Chem.-Int. Edit.,53(24),6105-6109.
MLA 胡峰,et al."Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion".Angew. Chem.-Int. Edit. 53.24(2014):6105-6109.
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