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学科主题: 氟化学
题名: Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion
其他题名: 银催化的脂肪酸乳液相脱羧三氟甲硫基化反应研究
作者: Hu F(胡峰); Shao XX(邵欣欣); Zhu DH(朱佃虎); Lv L(吕龙); Shen QL(沈其龙)
通讯作者: 沈其龙
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201402573
卷: 53, 期:24, 页:6105-6109
收录类别: SCI
英文摘要: A silver-catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of functional groups. The reaction was dramatically accelerated by its performance in an aqueous emulsion, which was formed by the addition of sodium dodecyl sulfate to water. It was proposed that the radical, which was generated from the silver-catalyzed decarboxylation in the "oil-in-water" droplets, could easily react with the trifluoromethylthiolating reagent to form the product.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38855
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Hu F,Shao XX,Zhu DH,et al. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion[J]. Angew. Chem.-Int. Edit.,2014,53(24):6105-6109.
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