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学科主题: 氟化学
题名: Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet-Triplet Energy Transfer (TTET) Processes
其他题名: 苯乙烯的可见光驱动单电子转移(SET)和三重态-三线态能量转移(TTET)的化学、区域和立体选择性三氟甲基化反应
作者: Lin QY(林卿玉)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: J. Org. Chem.
发表日期: 2014
DOI: 10.1021/jo502040t
卷: 79, 期:21, 页:10434-10446
收录类别: SCI
英文摘要: A process for tunable and chemo-, regio-, and stereoselective photocatalytic trifluoromethylation of styrenes was developed. Thermodynamically stable E-trifluoromethylated alkenes were prepared using Tognis reagent in the presence of Ru(bpy)(3)Cl-2 center dot 6H(2)O under visible light irradiation, whereas less thermodynamically stable Z-trifluoromethylated alkenes were obtained by employing Umemotos reagent and photocatalyst Ir(ppy)(3).
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38850
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.东华大学

Recommended Citation:
Lin QY,Xu XH,Qing FL. Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet-Triplet Energy Transfer (TTET) Processes[J]. J. Org. Chem.,2014,79(21):10434-10446.
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