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Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes
Alternative Title未活化末端烯烃的铜催化氧化三氟甲硫基化反应
Zhang K(张柯)1; Liu JB(刘建波)1; Qing FL(卿凤翎)1
Source PublicationChem. Commun.
AbstractA general method to form a C(SP3)-SCF3 bond via copper-mediated oxidative trifluoromethylthiolation of unactivated alkenes with stable nucleophilic AgSCF3 was developed. This protocol provides a direct and efficient access to a series of trifluoromethylthiolated allylic compounds with broad functional group tolerance.
Subject Area氟化学
Indexed BySCI
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Cited Times:65[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorQing FL(卿凤翎)
Recommended Citation
GB/T 7714
Zhang K,Liu JB,Qing FL. Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes[J]. Chem. Commun.,2014,50(91):14157-14160.
APA 张柯,刘建波,&卿凤翎.(2014).Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes.Chem. Commun.,50(91),14157-14160.
MLA 张柯,et al."Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes".Chem. Commun. 50.91(2014):14157-14160.
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