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学科主题: 氟化学
题名: Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles
其他题名: 铜催化的可构筑三氟甲基杂环化合物的炔烃的分子内carbotrifluoromethylation反应
作者: Wang YN(王亚南); Jiang M(蒋敏); Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Chem.-Eur. J.
发表日期: 2014
DOI: 10.1002/chem.201404386
卷: 20, 期:47, 页:15315-15319
收录类别: SCI
英文摘要: A mild and efficient copper-catalyzed intramolecular carbotrifluoromethylation of alkynes has been achieved in the presence of Togni reagent as trifluoromethylating reagent. The reaction tolerates a range of substrates to give a group of trifluoromethylated heterocycles with high selectivities. A plausible mechanism was proposed on the basis of experimental results.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38842
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Wang YN,Jiang M,Liu JT. Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles[J]. Chem.-Eur. J.,2014,20(47):15315-15319.
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