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Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles
Alternative Title铜催化的可构筑三氟甲基杂环化合物的炔烃的分子内carbotrifluoromethylation反应
Wang YN(王亚南); Jiang M(蒋敏); Liu JT(刘金涛)
2014
Source PublicationChem.-Eur. J.
Volume20Issue:47Pages:15315-15319
AbstractA mild and efficient copper-catalyzed intramolecular carbotrifluoromethylation of alkynes has been achieved in the presence of Togni reagent as trifluoromethylating reagent. The reaction tolerates a range of substrates to give a group of trifluoromethylated heterocycles with high selectivities. A plausible mechanism was proposed on the basis of experimental results.
Subject Area氟化学
DOI10.1002/chem.201404386
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38842
Collection中科院有机氟化学重点实验室
Corresponding AuthorLiu JT(刘金涛)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Wang YN,Jiang M,Liu JT. Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles[J]. Chem.-Eur. J.,2014,20(47):15315-15319.
APA 王亚南,蒋敏,&刘金涛.(2014).Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles.Chem.-Eur. J.,20(47),15315-15319.
MLA 王亚南,et al."Copper-Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated Heterocycles".Chem.-Eur. J. 20.47(2014):15315-15319.
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