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Organocatalytic aldol and domino Michael-aldol reactions of alpha, alpha-difluoro-beta-keto esters with acetone
Alternative Title有机催化的α,α-二氟-β-羰基酯与丙酮的aldol和domino Michael-aldol反应
Zhao Y(赵燕); Wang XJ(王小进); Cai CX(蔡晨新); Liu JT(刘金涛)
2014
Source PublicationJ. Fluor. Chem.
Volume165Pages:61-66
AbstractOrganocatalyzed reactions of alpha,alpha-difluoro-beta-keto esters with acetone were demonstrated. In the presence of L-proline, the Aldol reaction occurred under mild conditions to give the corresponding tertiary alpha,alpha-difluoroalcohols in good yields with high enantioselectivities. Using pyrrolidine as catalyst, the domino Michael-aldol reaction took place readily to give the corresponding addition products in high yields with excellent diastereoselectivities. (C) 2014 Elsevier B.V. All rights reserved.
Subject Area氟化学
DOI10.1016/j.jfluchem.2014.06.010
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38839
Collection中科院有机氟化学重点实验室
Corresponding AuthorLiu JT(刘金涛)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhao Y,Wang XJ,Cai CX,et al. Organocatalytic aldol and domino Michael-aldol reactions of alpha, alpha-difluoro-beta-keto esters with acetone[J]. J. Fluor. Chem.,2014,165:61-66.
APA 赵燕,王小进,蔡晨新,&刘金涛.(2014).Organocatalytic aldol and domino Michael-aldol reactions of alpha, alpha-difluoro-beta-keto esters with acetone.J. Fluor. Chem.,165,61-66.
MLA 赵燕,et al."Organocatalytic aldol and domino Michael-aldol reactions of alpha, alpha-difluoro-beta-keto esters with acetone".J. Fluor. Chem. 165(2014):61-66.
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