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学科主题: 氟化学
题名: Highly enantioselective direct Michael addition of 1,3-dicarbonyl compounds to beta-fluoroalkyl-alpha-nitroalkenes
其他题名: 1,3-二羰基化合物与β-氟烷基-α-硝基烯烃的高对映选择性Michael加成反应
作者: Zhao Y(赵燕)1; Wang XJ(王小进)1; Lin Y(林云)1; Cai CX(蔡晨新)1; Liu JT(刘金涛)1
通讯作者: 刘金涛
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.02.062
卷: 70, 期:15, 页:2523-2528
收录类别: SCI
英文摘要: Cinchona alkaloid catalysts were used in the Michael addition reaction of 1,3-dicarbonyl compounds to beta-fluoroalkyl-alpha-nitroalkenes for the first time. The catalytic system performed well over a broad scope of substrates including beta-keto esters and 1,3-diketones with high diastereoselectivities and excellent enantioselectivities (up to 99% ee) under mild conditions. A wide range of useful fluorinated chiral building blocks was synthesized. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38836
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.南京师范大学

Recommended Citation:
Zhao Y,Wang XJ,Lin Y,et al. Highly enantioselective direct Michael addition of 1,3-dicarbonyl compounds to beta-fluoroalkyl-alpha-nitroalkenes[J]. Tetrahedron,2014,70(15):2523-2528.
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