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学科主题: 氟化学; 金属有机化学
题名: A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes
其他题名: 一种普遍区域选择性地通过芳基重氮盐和RFCu(CH3CN)络合物合成全氟烷基芳基化合物的方法
作者: Jiang DF(姜东方); Liu C(刘超); Guo Y(郭勇); Xiao JC(肖吉昌); Chen QY(陈庆云)
通讯作者: 刘超 ; 陈庆云
刊名: Eur. J. Org. Chem.
发表日期: 2014
DOI: 10.1002/ejoc.201402820
期: 28, 页:6303-6309
收录类别: SCI
英文摘要: A mild method of converting arylamines into perfluoroalkylated arenes is described. Relatively stable RFCu(CH3CN) complexes are used as perfluoroalkylating agents, which react smoothly with arenediazonium salts to produce various perfluoroalkylarenes in good yields. Based on the results of clock trapping experiments with diallyl ether, a radical process might be involved in the reaction.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38831
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Jiang DF,Liu C,Guo Y,et al. A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes[J]. Eur. J. Org. Chem.,2014(28):6303-6309.
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