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Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates
Alternative TitleAu(I)/Cu(I)催化下醋酸炔丙酯的串联1,3-酰氧基迁移/三氟甲基化
Ji YL(季云龙)1; Lin JH(林锦鸿)1; Xiao JC(肖吉昌)1; Gu YC(顾玉诚)1
2014
Source PublicationEur. J. Org. Chem.
Issue35Pages:7948-7954
AbstractAu-I/Cu-I-co-catalyzed tandem 1,3-acyloxy migration/trifluoromethylation reaction of propargyl esters to give -trifluoromethyl enones in moderate yields and with excellent stereoselectivity is described. It is proposed that the reaction proceeds through the 1,3-acyloxy migration of the propargyl esters catalyzed by Au-I to produce an allenic intermediate, followed by its trifluoromethylation to give the final product.
Subject Area氟化学 ; 金属有机化学
DOI10.1002/ejoc.201403115
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38830
Collection中科院有机氟化学重点实验室
Corresponding AuthorLin JH(林锦鸿); Xiao JC(肖吉昌)
Affiliation1.中科院上海有机化学研究所
2.英国先正达公司
Recommended Citation
GB/T 7714
Ji YL,Lin JH,Xiao JC,et al. Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates[J]. Eur. J. Org. Chem.,2014(35):7948-7954.
APA 季云龙,林锦鸿,肖吉昌,&顾玉诚.(2014).Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates.Eur. J. Org. Chem.(35),7948-7954.
MLA 季云龙,et al."Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates".Eur. J. Org. Chem. .35(2014):7948-7954.
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