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学科主题: 氟化学; 金属有机化学
题名: Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates
其他题名: Au(I)/Cu(I)催化下醋酸炔丙酯的串联1,3-酰氧基迁移/三氟甲基化
作者: Ji YL(季云龙)1; Lin JH(林锦鸿)1; Xiao JC(肖吉昌)1; Gu YC(顾玉诚)1
通讯作者: 林锦鸿 ; 肖吉昌
刊名: Eur. J. Org. Chem.
发表日期: 2014
DOI: 10.1002/ejoc.201403115
期: 35, 页:7948-7954
收录类别: SCI
英文摘要: Au-I/Cu-I-co-catalyzed tandem 1,3-acyloxy migration/trifluoromethylation reaction of propargyl esters to give -trifluoromethyl enones in moderate yields and with excellent stereoselectivity is described. It is proposed that the reaction proceeds through the 1,3-acyloxy migration of the propargyl esters catalyzed by Au-I to produce an allenic intermediate, followed by its trifluoromethylation to give the final product.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38830
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.英国先正达公司

Recommended Citation:
Ji YL,Lin JH,Xiao JC,et al. Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates[J]. Eur. J. Org. Chem.,2014(35):7948-7954.
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