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学科主题: 氟化学
题名: Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes
其他题名: 以PhSO(NTBS)CF2H试剂对非活化烷基溴的亲核二氟甲基化反应: 偕二氟烯烃的便捷合成
作者: Shen X(沈晓); Liu QH(刘庆贺); Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Chin. J. Chem.
发表日期: 2014
DOI: 10.1002/cjoc.201400403
卷: 32, 期:8, 页:703-708
收录类别: SCI
英文摘要: An efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF2H has been developed. It is particularly remarkable that, when 1.5 equiv. of alkyl bromides are used, the substitution products are obtained in moderate to excellent yields. The prepared difluoro(phenylsulfonimidoyl) methylated alkanes can be readily transformed to gem-difluoroalkenes via base-mediated beta-elimination reaction.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38826
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Shen X,Liu QH,Ni CF,et al. Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes[J]. Chin. J. Chem.,2014,32(8):703-708.
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