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Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes
Alternative Title以PhSO(NTBS)CF2H试剂对非活化烷基溴的亲核二氟甲基化反应: 偕二氟烯烃的便捷合成
Shen X(沈晓); Liu QH(刘庆贺); Ni CF(倪传法); Hu JB(胡金波)
2014
Source PublicationChin. J. Chem.
Volume32Issue:8Pages:703-708
AbstractAn efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF2H has been developed. It is particularly remarkable that, when 1.5 equiv. of alkyl bromides are used, the substitution products are obtained in moderate to excellent yields. The prepared difluoro(phenylsulfonimidoyl) methylated alkanes can be readily transformed to gem-difluoroalkenes via base-mediated beta-elimination reaction.
Subject Area氟化学
DOI10.1002/cjoc.201400403
URL查看原文
Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38826
Collection中科院有机氟化学重点实验室
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Shen X,Liu QH,Ni CF,et al. Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes[J]. Chin. J. Chem.,2014,32(8):703-708.
APA 沈晓,刘庆贺,倪传法,&胡金波.(2014).Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes.Chin. J. Chem.,32(8),703-708.
MLA 沈晓,et al."Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes".Chin. J. Chem. 32.8(2014):703-708.
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