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学科主题: 氟化学
题名: Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines
其他题名: 叔丁基亚磺酰亚胺在可移除的PhSO2CF2基团促进下对芳炔的立体选择性[3+2]反应: 环状亚砜亚胺的合成及转化
作者: Ye WC(叶文超); Zhang LJ(张来俊); Ni CF(倪传法); Rong J(荣健); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c4cc05042h
卷: 50, 期:73, 页:10596-10599
收录类别: SCI
英文摘要: An unprecedented [3+2] cycloaddition between N-tert-butanesulfinyl imines and arynes provides a stereoselective method for the synthesis of cyclic sulfoximines. Not only does the difluoro(phenylsulfonyl) methyl group play an important role in facilitating the cycloaddition reaction, it can also be removed or substituted through the transformation of the difluorinated cyclic sulfoximines to cyclic sulfinamides.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38825
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Ye WC,Zhang LJ,Ni CF,et al. Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines[J]. Chem. Commun.,2014,50(73):10596-10599.
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