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学科主题: 氟化学
题名: Fluorinated Sulfoximines: Preparation, Reactions and Applications
其他题名: 含氟亚砜亚胺的制备、反应和应用
作者: Shen X(沈晓); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Eur. J. Org. Chem.
发表日期: 2014
DOI: 10.1002/ejoc.201402086
期: 21, 页:4437-4451
收录类别: SCI
英文摘要: The selective incorporation of fluorine atoms or fluorinated moieties into organic molecules has become a "hot" research topic in modern organic chemistry. However, selective and efficient synthesis of organofluorine compounds greatly depends on the development of powerful fluorination or fluoroalkylation reagents and reactions. In this context, the past decade has witnessed rapid research progress in the development of alpha-fluoro sulfoximines as versatile fluoroalkylation reagents. Many efficient nucleophilic, electrophilic and radical fluoroalkylation reactions based on alpha-fluoro sulfoximine reagents have been developed; among these, several chiral sulfoximine reagents were successfully used in the synthesis of enantiomerically enriched organofluorine compounds. It was found that alpha-fluoro sulfoximines show unique chemical behaviour characteristics (such as difluorocarbene and fluoroalkyl radical reactivities) significantly different from those of their non-fluorinated counterparts. In addition to the rapid development of fluorinated sulfoximines in organic synthesis, research into their application in materials science has also attracted increasing attention. Sulfoximines are important bioactive substances, and more recently the synthesis and application of fluorinated sulfoximines has attracted much attention in life sciences and the pharmaceutical industry. In this microreview we summarize the preparation, reactions and applications of fluorinated sulfoximines (mainly alpha-fluoro sulfoximines).
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38824
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Shen X,Hu JB. Fluorinated Sulfoximines: Preparation, Reactions and Applications[J]. Eur. J. Org. Chem.,2014(21):4437-4451.
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