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Fluorinated Sulfoximines: Preparation, Reactions and Applications
其他题名含氟亚砜亚胺的制备、反应和应用
Shen X(沈晓); Hu JB(胡金波)
2014
发表期刊Eur. J. Org. Chem.
期号21页码:4437-4451
摘要The selective incorporation of fluorine atoms or fluorinated moieties into organic molecules has become a "hot" research topic in modern organic chemistry. However, selective and efficient synthesis of organofluorine compounds greatly depends on the development of powerful fluorination or fluoroalkylation reagents and reactions. In this context, the past decade has witnessed rapid research progress in the development of alpha-fluoro sulfoximines as versatile fluoroalkylation reagents. Many efficient nucleophilic, electrophilic and radical fluoroalkylation reactions based on alpha-fluoro sulfoximine reagents have been developed; among these, several chiral sulfoximine reagents were successfully used in the synthesis of enantiomerically enriched organofluorine compounds. It was found that alpha-fluoro sulfoximines show unique chemical behaviour characteristics (such as difluorocarbene and fluoroalkyl radical reactivities) significantly different from those of their non-fluorinated counterparts. In addition to the rapid development of fluorinated sulfoximines in organic synthesis, research into their application in materials science has also attracted increasing attention. Sulfoximines are important bioactive substances, and more recently the synthesis and application of fluorinated sulfoximines has attracted much attention in life sciences and the pharmaceutical industry. In this microreview we summarize the preparation, reactions and applications of fluorinated sulfoximines (mainly alpha-fluoro sulfoximines).
学科领域氟化学
DOI10.1002/ejoc.201402086
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收录类别SCI
语种英语
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38824
专题中科院有机氟化学重点实验室
通讯作者Hu JB(胡金波)
作者单位中科院上海有机化学研究所
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Shen X,Hu JB. Fluorinated Sulfoximines: Preparation, Reactions and Applications[J]. Eur. J. Org. Chem.,2014(21):4437-4451.
APA 沈晓,&胡金波.(2014).Fluorinated Sulfoximines: Preparation, Reactions and Applications.Eur. J. Org. Chem.(21),4437-4451.
MLA 沈晓,et al."Fluorinated Sulfoximines: Preparation, Reactions and Applications".Eur. J. Org. Chem. .21(2014):4437-4451.
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