中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals
其他题名: 过渡金属辅助下对芳烃的选择性二氟烷基化反应研究进展
作者: Gao B(高兵); Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Chimia
发表日期: 2014
DOI: 10.2533/chimia.2014.414
卷: 68, 期:6, 页:414-418
收录类别: SCI
英文摘要: Fluorinated compounds are of significant importance in various fields due to their unique chemical, physical, and biological properties. Accordingly, the incorporation of fluorine atom(s) or fluorine-containing functionalities into organic molecules has received considerable attention. For decades, extensive reports and reviews mainly focused on the fluorination and perfluoroalkylation (especially trifluoromethylation) whereas the preparation of partially fluorinated compounds was less developed. Difluoromethylated arenes and their derivatives (ArCF2R, R not equal F, R-f, H) have been found to be as important in pharmaceuticals as trifluoromethylated arenes. However, it is only recently that these compounds have experienced a revival of interest from synthetic chemists. The direct construction of carbon(sp(2)) carbon(sp(3)) bonds via transition metal-mediated cross-coupling reactions represents one of the most straightforward strategies for the introduction of difluoromethylene moieties (CF2R, R not equal F, R-f) to aromatic compounds. This mini-review focuses on recent advances of this research topic from both synthetic and mechanistic perspectives.
语种: 英语
相关网址: 查看原文
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38823
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2014322.pdf(190KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所

Recommended Citation:
Gao B,Ni CF,Hu JB. Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals[J]. Chimia,2014,68(6):414-418.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[高兵]'s Articles
[倪传法]'s Articles
[胡金波]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[高兵]‘s Articles
[倪传法]‘s Articles
[胡金波]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2014322.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace