SIOC OpenIR  > 中科院有机氟化学重点实验室
Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals
其他题名过渡金属辅助下对芳烃的选择性二氟烷基化反应研究进展
Gao B(高兵); Ni CF(倪传法); Hu JB(胡金波)
2014
发表期刊Chimia
卷号68期号:6页码:414-418
摘要Fluorinated compounds are of significant importance in various fields due to their unique chemical, physical, and biological properties. Accordingly, the incorporation of fluorine atom(s) or fluorine-containing functionalities into organic molecules has received considerable attention. For decades, extensive reports and reviews mainly focused on the fluorination and perfluoroalkylation (especially trifluoromethylation) whereas the preparation of partially fluorinated compounds was less developed. Difluoromethylated arenes and their derivatives (ArCF2R, R not equal F, R-f, H) have been found to be as important in pharmaceuticals as trifluoromethylated arenes. However, it is only recently that these compounds have experienced a revival of interest from synthetic chemists. The direct construction of carbon(sp(2)) carbon(sp(3)) bonds via transition metal-mediated cross-coupling reactions represents one of the most straightforward strategies for the introduction of difluoromethylene moieties (CF2R, R not equal F, R-f) to aromatic compounds. This mini-review focuses on recent advances of this research topic from both synthetic and mechanistic perspectives.
学科领域氟化学
DOI10.2533/chimia.2014.414
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收录类别SCI
语种英语
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38823
专题中科院有机氟化学重点实验室
通讯作者Hu JB(胡金波)
作者单位中科院上海有机化学研究所
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GB/T 7714
Gao B,Ni CF,Hu JB. Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals[J]. Chimia,2014,68(6):414-418.
APA 高兵,倪传法,&胡金波.(2014).Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals.Chimia,68(6),414-418.
MLA 高兵,et al."Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals".Chimia 68.6(2014):414-418.
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