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学科主题: 氟化学
题名: Recent Advances in the Synthetic Application of Difluorocarbene
其他题名: 二氟卡宾在合成应用中的最新进展
作者: Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Synthesis
发表日期: 2014
DOI: 10.1055/s-0033-1340856
卷: 46, 期:7, 页:842-863
收录类别: SCI
英文摘要: Difluorocarbene is a versatile, reactive intermediate for use in organic synthesis. Over the past decade, significant progress has been made in difluorocarbene chemistry owing to the increasing demand for various fluorinated molecules. Not only the substrate scope for some classical difluorocarbene reagents has been largely expanded, but also new and environmentally friendly difluorocarbene reagents for difluoromethylation and gem-difluorocyclization have been developed. This review summarizes the difluoromethylation, gem-difluorocyclopropanation, gem-difluorocyclopropenation, gem-difluoroolefination, and trifluoromethylation achieved in the last decade using both the classical and the new difluorocarbene sources.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38820
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Ni CF,Hu JB. Recent Advances in the Synthetic Application of Difluorocarbene[J]. Synthesis,2014,46(7):842-863.
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