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SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes
其他题名: 偕二氟烯烃在银调控下的氟化自偶联反应
作者: Gao B(高兵); Zhao YC(赵延川); Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol403083e
卷: 16, 期:1, 页:102-105
收录类别: SCI
英文摘要: A novel silver(I)-fluoride-mediated homocoupling reaction of beta,beta-difluorostyrene derivatives is described. The transformation is initiated via nucleophilic addition of silver(I) fluoride to beta,beta-difluorostyrenes, which is followed by dimerization of the corresponding benzylsilver intermediates. The reaction shows good substrate scope, functional group tolerance, and represents the first report on the reactivity of (alpha-trifluoromethyl)benzylsilver species.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/38814
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Gao B,Zhao YC,Ni CF,et al. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes[J]. Org. Lett.,2014,16(1):102-105.
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